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The Chemistry of Fireworks

Let’s explore the chemical reaction behind the vibrant display of colors of fireworks.

Fireworks captivate us with a vibrant display of light and colors. Behind these lies a complex series of chemical reactions, from the initial ignition to the final burst of colors. Let’s explore the chemistry of fireworks.

Oxidizers

  • A chemical rich in oxygen (nitrates, chlorates, or perchlorates)
  • Provides the oxygen necessary for the mixture to burn.
  • The oxidizing agent will receive the electrons and cause the release of energy.

Fuel (Gunpowder)

  • Usually composed of charcoal and sulfur.
  • Gunpowder was originally discovered by Chinese alchemists
  • It was made with a combination of honey, sulfur, and saltpeter (potassium nitrate). Charcoal replaced honey.
  • In modern times, gunpowder has a weight ratio of 75:15:10 saltpeter:charcoal:sulfur, which hasn’t changed since 1781!

Here’s the chemical reaction of gunpowder:

\[6KNO_3 + C_7H_4O + 2S \to K_2CO_3 + K_2SO_4 + K_2S + 4CO_2 + 2CO + 2H_2O + 3N_2 \]

Colorant

  • Metals burn in different colors due to the electron arrangements in the outer shell of the metal’s nucleus, and the emission of different wavelengths of light.

Binder

  • Usually made of dextrin
  • Brings together all the components
  • Serves as the fuel after ignition
  • Makes sure fireworks don’t unexpectedly explode
  • Serves as the source of electrons that will be burned later.
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